here's something I found that should be required reading for all of us.
[Editor's Note: After the conversation following our introduction of the Hemmings Motor News Motor Oil last month, we turned to our tech guru, Jim O'Clair, for an explanation of the problems classic car owners have when choosing a modern motor oil.]
There has been a lot of confusion in the last few years about the lowering of zinc and phosphorus levels in modern oils and how these lower levels relate to classic and performance engines using standard flat tappet lifters – that is, just about every car built before the Eighties. The concern involves the use of the new lower zinc/phosphorus-content ILSAC (multi-viscosity) oils, readily available on shelves at auto parts stores everywhere, and how compatible they are with these older engines.
When anyone mentions zinc, they are actually referring to zinc dialkyldithiophosphate, a compound invented by Castrol for use in mineral-based oils orzinc di-thiophosphate (ZDTP), which is normally used in synthetic oils. Both have been used as an anti-wear ingredient in engine oil for many years. The zinc and phosphorus ingredients appear to be most effective when they are used together. ZDDP/ZDTP is one of many additives that are put into conventional motor oil to improve its lubrication qualities. Other ingredients such as boron and molybdenum are also added as lubricant enhancers.
What was discovered through oil testing by several engine component manufacturers is that many older engines experience a short period of time during engine start-up where critical lubrication is insufficient between metal-to-metal lubrication points when using modern oils with reduced amounts of ZDDP/ZDTP. These same enhancers unfortunately have their downside: The phosphorus in this compound creates carbon buildup in engine bores and valvetrains, and both compounds can also lead to the early demise of catalytic converters. For this reason, the industry has been phasing out zinc and phosphorus levels since 1994, when the American Petroleum Institute’s SH designation became the industry standard, and levels have been further reduced in each subsequent API rating for engine oils. Manufacturers have tried adding more boron to offset the effects of the reduced zinc and phosphorus levels; however, the dry start protection does not measure up to those using more ZDDP/ZDTP. This has opened up a whole new market for zinc/phosphorus additives for oil and many camshaft and engine manufacturers now recommend that an additive be used in initial break-in and for regular use.
All engine oils are rated for viscosity by the SAE as well as additive content by the API; passenger car ratings are two-letter designations that start with “S.” Heavy-duty or off-road equipment ratings start with “C.” The current API oil rating for passenger cars (gasoline engines) is SM and for trucks (diesel engines) CJ-4. Within these designations, you can determine how much zinc and how many other chemicals are present in the ILSAC (multi-viscosity) oils. These levels do not apply to straight-weight oils. If levels in the ILSAC oils are too high for the API specification, they cannot be rated for the current specification unless the container specifies “for racing or off-road use only” or “for use in classic cars.” This has caused oil companies to reduce levels of many additives, including zinc and phosphorus, to the required maximum in order to meet the current specification. Listed here are the current specifications for maximum amounts of additives to achieve the API ratings. P is phosphorus, Zn is zinc, and B is boron. Each figure is total parts per million of additives. These can also be roughly expressed in percentages by multiplying by .0001 (1301 PPM = .13 percent, 994 PPM = .099 percent)
API
P
Zn
B
SJ
1301
1280
151
CI-4
1150
1374
83
SL
994
1182
133
CJ-4
819
1014
26
SM
770
939
127
Most engine and engine component manufacturers recommend zinc and phosphorus content of more than 1,200 PPM for break-in; in fact, many will void warranties on camshafts or crate engines if this minimum is not found in the oil sample you supply when returning broken parts for warranty. For this reason, many manufacturers produce their own zinc additives or oils with supplementary zinc included; GM even offers its own break-in oil with additional ZDDP. With respect to readily available oil, you can see from the chart that, if you can find oil still on the shelf rated SJ or SL, you can use them, but you are right on the cusp of voiding a warranty. New SM oils are just not going to cut it unless they have a zinc additive to boost the rating and one of the zinc supplements should be used with these oils or oils containing additional ZDDP additives are recommended. Some enthusiasts have recommended using commercially rated CI-4 15W40 diesel oil to meet the zinc and phosphorus additive requirement; however, CI-4 is an old specification and hard to locate. You can see that the CJ-4 specification that now supersedes it is well below acceptable levels. Our best recommendation is that you contact your oil supplier for exact additive contents. Many straight-weight oils do not have to meet the ILSAC API specifications to be sold as SM or CJ-4, so this may be an alternative. Classic car oils with elevated levels of ZDDP/ZDTP are also being offered by many suppliers. Regardless, if you are purchasing off-the-shelf oil for your classic car, ILSAC multi-viscosity oils rated SM or CJ-4 should have stated zinc and phosphorus additive supplements for use in older engines or an additional separate additive should be purchased and used with the new oil. As the new API rating SN becomes available in the next year, even more caution should be taken as the levels will be reduced even further.
Over the years there has been an overabundance of engine oil myths. One was that the only good oils were oils made from "Pure Pennsylvania Crude Oil." This one got started before the Second World War when engine oil was crude oil with very minimal refining, and crude oil from Pennsylvania made better engine oil than Texas or California crude. With modern refining, almost any crude can be made into good engine oil.
The next myth was that "modern" detergent engine oils were bad for older engines. This one got started after the Second World War, when the government no longer needed all the detergent oil for the war effort, and it hit the market as Heavy-Duty oil. These new detergent oils gave the pre-war cars, which had been driven way past their normal life and were full of sludge and deposits, a massive enema. In some cases bad things happened such as increased oil consumption – the piston rings were completely worn out and the massive piston deposits were the only thing standing between merely high and horrendous oil consumption. If detergent oils had been available to the public during the war, this myth never would have started.
Amazingly there are still a few people today, 60 years later, who believe that they need to use non-detergent oil in their older cars. Apparently it takes about 75 years for an oil myth to die.
Then there is the myth that new engines will not break-in on synthetic oils. Apparently there was an aircraft engine manufacturer who once put out a bulletin to this effect. Clearly the thousands and thousands of cars filled with Mobil 1 as factory-fill, which have broke-in quite well, should have put this one to rest. However this one is only 40 years old, so it has another 35 years to live.
All of these myths have a common theme; newer oils are bad. And this brings us to the latest myth – new "Starburst"/ API SM engine oils are bad for older cars because the amount of anti-wear additive in them has been reduced. This one has gotten big play in the antique and collector car press lately. The anti-wear additive being discussed is zinc dithiophosphate (ZDP).
Before debunking this myth we need to look at the history of ZDP usage in engine oil.
ZDP has been used for over 60 years as an additive in engine oils to provide wear protection and oxidation stability. Unfortunately, ZDP contains phosphorus, and phosphorus is a poison for automotive catalysts. For this reason ZDP levels have been reduced by about 35% over the last 10-15 years down to a maximum of 0.08% for "Starburst"/API SM oils.
Zinc dithiophosphate was first added to engine oil to control copper/lead bearing corrosion. Starting in 1942, a Chevrolet Stovebolt engine with aftermarket copper/lead insert bearing connecting rods was the standard oil test. The insert bearings were weighed before and after test for weight loss due to corrosion. The phosphorus levels of oils that passed the test were in the 0.03% range.
In the mid 1950s Oldsmobile got in a horsepower war with its Rocket engine against the Chrysler Hemi. Both companies went to high-lift camshafts and both got into camshaft scuffing and wear problems very fast. There were three solutions. Better camshaft and lifter metallurgy, phosphating the camshaft, and increasing the phosphorus level from ZDP up to the 0.08% range. Another outcome was a battery of industry wide "Sequence" oil tests. Two of theses tests were valve-train scuffing/wear tests.
Knowing that this higher level of ZDP was good for flat-tappet valve-train scuffing and wear, some oil companies dumped even more in thinking that they were offering the customer even more protection. However it was soon learned that while going above something like 0.14% phosphorus might decrease break-in scuffing, it increased longer term wear. At about 0.20% phosphorus the ZDP started attacking the grain boundaries in the iron, resulting in camshaft spalling.
Later in the 1970s, the ZDP level was pushed up to the 0.10% phosphorus range as it was a cheap and effective antioxidant, and increased antioxidancy was needed to protect the oil in Cadillacs pulling Airstream trailers from thickening to the point of not pumping. Recently, the need for this higher level of ZDP for protecting the oil from thickening has been greatly reduced with the introduction of more modern ashless antioxidants that contain no phosphorus.
Enough history, now getting back to the myth that "Starburst/API SM oils are no good for older cars. The argument put forth by the myth believers is that while these oils work perfectly well in modern gasoline engines equipped with roller
camshafts, they will cause catastrophic wear in older engines equipped with flat-tappet camshafts.
The "Starburst"/API SM oil standards were developed by a group of OEM, oil additive company, and oil company experts. When developing any new engine oil standard the issue of "backward compatibility" always comes up, and indeed the group of experts spent a lot of time researching this issue. Various oil and additive companies ran "no harm" tests on older cars with the new oils. No problems were uncovered.
The new specification contains two valve-train wear tests. One is the Sequence IVA Test which tests for camshaft scuffing and wear using a 2.4L Nissan single overhead camshaft engine with slider finger followers. The wear limits were tightened from the previous oil specification which contained a phosphorus limit of 0.10%. The second is the Sequence IIIG Test which evaluates cam and lifter wear. A current production GM Powertrain 3.8L engine with the valve train replaced with a flat tappet system similar to those used in the 1980s is used. The only reason that this test engine uses this older valve train design is to insure that older engines are protected. All "Starburst"/API SM oil formulations must pass these two tests.
In addition to the protection offered by these two valvetrain wear tests and the new testing which was conducted on the formulations containing lower levels of ZDP, a review of the knowledge gained over the years in developing previous categories also indicates that no problem should be expected. The new "Starburst"/API SM oils contain about the same percentage of ZDP as the oils that solved the camshaft scuffing and wear issues back in the 1950s. They do contain less ZDP than the oils that solved the oil thickening issues in the 1960s, but that is because they now contain high levels of ashless antioxidants that were not commercially available in the 1960s.
The oil’s ZDP level is only one factor in determining the life of an older camshaft or a new aftermarket camshaft. Most of the anecdotal reports of camshaft failures attributed to the newer oils appear to be with aftermarket camshafts. Breaking in extremely aggressive aftermarket camshafts has always been problem. The legendary Smokey Yunick wrote that his solution to the problem was to buy multiple camshafts and simply try breaking them in until he found one that survived break-in without scuffing.
Despite the pains taken in developing special flat tappet camshaft wear tests that these new oils must pass and the fact that the ZDP level of these new oils is comparable to the level found necessary to protect flat tappet camshafts in the past, there will still be those who want to believe the myth that "new oils will wear out older engines." Like other myths before it, history teaches us that it will take about 75 years for this one to die also.
Chuck am I right in assuming that the fatter your engine runs the more frequent oil changes should be? I was told not to use synthetic oil in my car is this a good practice?
Chuck am I right in assuming that the fatter your engine runs the more frequent oil changes should be? I was told not to use synthetic oil in my car is this a good practice?
I think the second paragraph of Chucks is relevant to synthetic . This stuff will enter and escape from places conventional oil never would . So you hear about blow by, leaks and more. Is this the result of the oil or the engine? Most engine damage occurs at start up . known fact because the oil is to thick to lubricate / pump properly this is the area synthetic excels over conventional. Seeing your oil pressure gauge maxed out at idle doesn't mean the components are being properly oiled . All it means is your pumps maxed out and dumping oil straight back to the pan and this is going to increase as the rpm get higher . Id much rather use thinner oil and see the pressure rise as the rpm increase and let the oil do what its meant to do, lubricate and cool the engine. from my own experiments on old engines I got 5 years and roughly 80.000 miles using synthetic on a 400 dollar inline 6 . Blown head gasket washed a cylinder ended it . I intend to do the same with its 200.00 dollar replacement.
Adding to what Slim said, all new(er) cars call for thinner oils. My wife's new Dodge calls for 5W20, and I've been using 0W40 Synthetic in my Cummins for almost 120,000 miles, cuz I want that oil to get where its needed ASAP.
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If brains were wire, some couldn't short circuit a firefly.
There is a decent little book written by an Aussie about choosing oil for older cars. It's called "Which Oil" ISBN 978-1-845843-65-6 I picked my copy up at Coles. It wasn't cheap at $20 for a little wee book, but it is jam packed with info and I think a very good reference for various oil substitutions in old car engines, gearboxes and trannies. Lots of science and graphs too for those who like that kind of thing. Fred
"Then there is the myth that new engines will not break-in on synthetic oils. Apparently there was an aircraft engine manufacturer who once put out a bulletin to this effect. Clearly the thousands and thousands of cars filled with Mobil 1 as factory-fill, which have broke-in quite well, should have put this one to rest. However this one is only 40 years old, so it has another 35 years to live."
All cars with factory fills of synthetic oils are roller camshaft vehicles. All the major cam manufacturers still recommend using dead dinosaur based oil (preferably break-in oil or normal oil with an added suppliment) for flat tappet camshaft. Apparently the synthetic is too good at lubricating for the proper wear mating of the cam and lifters.
The new version of the GM EOS has been out for a few years. They took the old one off the shelf in around 2007ish, and it took a year for the new one to come out. The old version apparently was killing sensors when used in newer vehicles.
The consistent problem I have with synthetic, gasket leaks in older engines..if you have weak or cork gasketsit will leak for sure..if there is any weak area in the gasket it wash it clean and find a leak..other wise I have many engines on synthetic (amsoil is my choice) I service a surprizing number of engines in excess of 400,000 MILES and still giving good service with no major engine tear-down..I usually use conventional oil to break in the cam and make sure everything is well lubed with assembly lube..Then make sure the oil pump is run to get oil pressure into everything..Then an oil and filter change after about 2 hrs running..my old shop truck 98 Dakota, 5.2 running 428,000 ks still only uses a liter in about a year and gets an oil and filter once a year ..on Amsoil....engine still ticks away and passes every e-test perfect..I hate to say this ..It only encourages Hemi ....
-- Edited by fatchuk on Thursday 21st of November 2013 06:15:47 AM
Th.my old shop truck 98 Dakota, 5.2 running 428,000 ks still only uses a liter in about a year and gets an oil and filter once a year ..on Amsoil....engine still ticks away and passes every e-test perfect..I hate to say this ..It only encourages Hemi ....